A graduated neutral density, or grad, is used to reduce the difference in light range between bright and shadow areas of a scene. In the following first figure, you can see that in order to capture detail in the ground, the sky details are blown out with very little detail. Using a two-stop grad, I've darkened the sky by two stops without affecting the foreground at all, letting me capture more sky detail (second figure).
Tip: You can use a polarizer as a neutral-density filter, too. Doing so gives you as much as two stops of exposure latitude when adjusted for maximum effect.
The other type of neutral-density filter is solid and is used to extend the exposure for things like blurred water image. You can get these in different strengths.
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